This one comes from the land of Mozilla: http://blog.mozilla.com/dmandelin/2011/06/30/a-short-guide-to-interviewing/

1. Greet the candidate and introduce yourself.
2. Ask about experience listed on the resume.
3. Ask about interests to learn about fit and motivation.
4. Ask technical questions similar to what comes up on the job.
5. Invite the candidate to ask you about anything.

More details are in Dave Mandelin's short guide to interviewing, but that covers the main points.

This is relevant to the hiring A players Convo.

Items 2, 3, and 4 really help us ascertain if the candidate has the right skills, attitude, and culture for a given position within a company.