Batman vs. Black Mercy
Normally Batman is fairly strong against psychic and emotional attacks. For example, he fared well versus Scarecrows fear toxin and versus Dr. Destiny's psychic manipulation. Black Mercy got a hold of him for a minute though!
This vid is kind of long, but for those who liked the Scarecrow delusion in Batman: Arkham Asylum (fantastic game!) it's worth watching again:
The game developers did such an awesome job of making you experience the hallucination alongside Batman. The way the screen starts slowly tilting to the side, and how the voices quietly start and then slowly get louder. Finally, you just get lost and confused in the morgue from hitting dead-ends, then turning around and finding the way back was not how you remembered.
Then there was the fact that Bats is hallucinating in a morgue, with all that emotional baggage starting to come out...
Batman vs. Dr. Destiny in the Justice League episode Only a Dream, Part II. By this point in the story, Dr. Destiny had at some point gotten the best of everyone except Martian Manhunter and Bats:
Arkham cosplay: http://9gag.com/gag/5401555
I should start a "General Discussion of Batman" convo for you.
Or at least a "General Discussion of Arkham"...